E-700 POLYESTER Part A MSDS Sheet

MATERIAL SAFETY DATA SHEET:

E-700 POLYESTER Part [ A ]		Emergency Number Chem. Tel 1-800-255-3924

1. CHEMICAL PRODUCT IDENTIFICATION: E-700 POLYESTER
Product Name: Formulation 291-22/2 Component I Product Code: E-700 Chemical Family: Non-Pigmented Polyacrylate/Polyester Resin Solution

2. COMPOSITION/INFORMATION ON INGREDIENTS:
INGREDIENT NAME /CAS NUMBER	EXPOSURE LIMITS		CONCENTRATION (%)
	HAZARDOUS INGREDIENTS

Butyl Acetate 123-86-4
	OSHA:150..00 ppm TWA 200.00, ppm STEL ACGIH: 150.00 ppm TWA 200.00 ppm STEL		10.7%

Titanium Dioxide (Ti02) 13463-67-7
	OSHA. 10.00 mg/m3 TWA Total Dust 5.00 mg/m3 TWA Respirable Dust ACGIH: 10.00 mg/m3 TWA		32.3%


Calcium Long Chain Alkaryl Sulfonate
	OSHA.- Not Established ACGIH: Not Established		less than 2.0%
The chemical identity of this ingredient is withheld as confidential business information by the supplier

Light Aromatic Naphtha 64742-95-6 .
	OSHA.- Not Established ACGIH: Not Established		less than 2.0%
Supplier recommends exposure limit of 100 ppm TWA

Methyl n-Amyl Ketone (MAK) 110-43-0
	OSHA : 100.000 ppm TWA 465.000 mg/m3 TWA ACGIH: 50.000 ppm TWA 233.000 mg/m3 TWA		2.2%

Acetic Acid Ester 88230-35-7
	OSHA : Not Established ACGIH: Not Established Supplier: 50.000 ppm		13.3%

Crystalline Silica (Quartz) 14808-60-7
	OSHA: 100 mg/m3 TWA Respirable Dust ACGIH: 100 mg/m3 TWA Respirable Dust		11%

3. PHYSICAL PROPERTIES:

PHYSICAL FORM	Liquid
COLOR	White
ODOR	Of solvent
BOILING POINT	Not established
MELTING/FREEZING POINT	Not established
SOLUBILITY IN WATER	Resin: Insoluble
SPECIFIC GRAVITY	1.43
BULK DENSITY	Approximately 11.9 lbs/gal
% VOLATILE BY WEIGHT	Approximately 30%
VAPOR PRESSURE	Not established

4. FIRE AND EXPLOSION DATA:
FLASH POINT:		Not established {BA: 81 F (27 C)}
FLAMMABLE LIMITS:
	UPPER EXPLOSIVE LIMIT (UEL) (%):	7.6 BA
	LOWER EXPLOSIVE LIMIT (LEL)(%):	1.7 BA
	UPPER EXPLOSIVE LIMIT (UEL)(%):	7.9 @ 250 C MAK
	LOWER EXPLOSIVE LIMIT (LEL)(%):	1.1 @ 150 C MAK

EXTINGUISHING MEDIA:		Dry Chemical; Carbon Dioxide; Foam

SPECIAL FIRE FIGHTING PROCEDURES:
	Full emergency equipment with self-contained breathing apparatus should be worn. During a fire irritating, toxic gases (see Reactivity Data) and smoke are present from decomposition/combustion. Isolate from heat, electrical equipment, sparks and open flame. Closed container may explode when exposed to extreme heat. Use cold water spray to cool fire-exposed containers to minimize risk of rupture. Solvent vapors may be heavier than air. Under conditions of stagnant air, vapors may build up and travel along the ground to an ignition source which may result in a flash back to the source of the vapors.

5. HUMAN HEALTH DATA:

ROUTE (S) OF ENTRY:
	Inhalation; Skin Contact; Skin Absorption; Eye Contact

HUMAN EFFECTS AND SYMPTOMS OF OVEREXPOSURE:
	ACUTE INHALATION
		Solvent vapors are irritating to the eyes, nose, throat and respiratory tract resulting in red, itchy eyes, dryness the throat and tightness in the chest. Other possible symptoms of overexposure include headache, nausea, narcosis, fatigue and loss of appetite. At 200 ppm of butyl acetate, persons have developed irritation of the eyes, nose and throat. These symptoms were severe at 300 ppm of butyl acetate. Overexposure to crystalline silica and titanium dioxide cause upper respiratory tract irritation. Symptoms may include coughing and shortness of breath.

	CHRONIC INHALATION
		Chronic exposure to organic solvents has been associated with various neurotoxic effects including permanent brain and nervous system damage. Symptoms include loss of memory, loss of intellectual ability, and loss of coordination. Excessive exposure to airborne crystalline silica can cause fibrotic lung damage, with scaring of the lungs and with coughing and shortness of breath. This condition is called "silicosis".

	ACUTE SKIN CONTACT
		Repeated or prolonged skin contact with solvents can result in dry, defatted and cracked skin causing increased susceptibility to infection. In addition, irritation (i.e. redness, swelling ) which may develop into dermatitis (inflammation) may occur from skin contact. Solvents can penetrate the skin causing effects similar to those identified under acute inhalation symptoms

	CHRONIC SKIN CONTACT
		Chronic skin exposure to the solvent may cause effects similar to those identified under chronic inhalation effects.

	ACUTE EYE CONTACT
		Liquid, aerosols or vapors are severely irritating to the eyes and can cause pain, tearing, redness and swelling. If left untreated, corneal damage can occur and injury is slow to heal. However, damage is usually reversible. See Section VI for treatment. Titanium dioxide can cause uncomfortable deposits in the eyes, ears and nose, but does not cause any toxic effect or disease when exposure is kept below the TLV.

	CHRONIC EYE CONTACT
		Prolonged vapor contact may cause conjunctivitis.

	ACUTE INGESTION
		Can result in irritation in the mouth, stomach tissue and digestive tract. Symptoms can include sore throat, abdominal pain, nausea, vomiting and diarrhea. Vomiting may cause aspiration resulting in chemical pneumonitis.

	CHRONIC INGESTION
		None determined.

	CARCINOGENICITY
		NTP :	Not listed
		IARC :	Crystalline silica has been classified by IARC as Group 2A - "there is limited evidence of carcinogenicity in humans and sufficient evidence of carcinogenicity in experimental animals" (IARC Monographs, Vol. 42).
		OSHA :	Not regulated
		OTHER :

	MEDICAL CONDITIONS
		None determined.

	EXPOSURE LIMITS :
		Not established for this product as a whole, refer to Section II for exposure limits of hazardous constituents.

6. EMERGENCY AND FIRST AID PROCEDURES:
FIRST AID FOR EYES:
	Flush with clean, lukewarm water (low pressure) for at least 15 minutes while holding eyelids open. Obtain medical attention if irritation persists..
FIRST AID FOR SKIN:
	Remove contaminated clothing immediately. Wash affected areas thoroughly with soap and water. Wash contaminated clothing thoroughly before reuse.
FIRST AID FOR INHALATION:
	Move to an area free from risk of further exposure. Administer oxygen or artificial respiration as needed. Obtain medical attention.
FIRST AID FOR INGESTION:
	DO NOT INDUCE VOMITING. Give a glass of milk or water to drink. DO NOT GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. Consult a physician.
NOTE TO PHYSICIAN:
	None Mentioned.

7. EMPLOYEE PROTECTION RECOMMENDATIONS:
EYE PROTECTION REQUIREMENTS:
	Liquid chemical goggles or full-face shield. Contact lenses should not be worn.
SKIN PROTECTION REQUIREMENTS:
	Permeation resistant gloves (butyl rubber, nitrile rubber). Cover as much of the exposed skin area as possible with appropriate clothing. If skin creams are used, keep the area protected only by the cream to a minimum.
RESPIRATORY/VENTILATION REQUIREMENT:
	Exhaust ventilation sufficient to keep t airborne concentrations of solvents and other hazardous constituents in t workplace below their respective TLVs or other appropriate exposure limit must be utilized. Exhaust air may need to be cleaned by scrubbers or filters to reduce environmental contamination. Curing ovens must be ventilated to prevent the build up of explosive atmospheres and to prevent off gases from entering the work place. in addition, a respirator that '_ recommended or approved for use in organic vapor containing environments (air purifying or fresh air ,supplied) may be necessary. In spray applications, an organic vapor/ particulate respirator or air supplied unit is necessary. Consider type of application and environmental concentrations. The use of a positive pressure supplied air respirator is mandatory when: airborne concentrations are not known; when levels are 10 times the appropriate TLV; or if spraying is performed in a confined space or area with limited ventilation. Take into account other materials being used concurrently. Observe OSHA regulations for respirator use (29 CFR 1910.134).
MONITORING:
	None Mentioned.
MEDICAL SURVEILLANCE:
	None Mentioned.
ADDITIONAL PROTECTIVE MEASURES:
	Safety showers and eye wash stations should be easily accessible to the work area.

8. REACTIVITY DATA:
STABILITY:
		This is a stable material.
HAZARDOUS POLYMERIZATION:
	Will not occur.
INCOMPATIBILITIES:
		Trimethylol propane s used in the manufacture of the polyester resin; therefore, it should not be combined with phosphorus containing materials because highly toxic fumes can be emitted in a fire situation.
INSTABILITY CONDITIONS:
		None determined
DECOMPOSITION PRODUCTS:
		By fire: C0, C02
9. SPILL AND LEAK PROCEDURES:

SPILL OR LEAK PROCEDURES:
		Evacuate non-essential personnel. Remove all sources of ignition and ventilate the area. Equip clean-up crew with appropriate protective equipment (i.e., clothing, respiratory, etc. See Employee Protection Recommendations). Dike or impound spilled material a:: control further spillage if feasible. Notify appropriate authorities if necessary. Cover spill with sawdust, vermiculite, Fuller's earth or other absorbent material; pour liquid decontaminate over spillage and allow to react for at least 10 min. Collect material in open containers and add further amounts of decontamination solution. Remove containers to safe place and cover loosely. Wash down area with liquid decontaminant and flush area with water.
NEUTRALIZATION CHEMICALS
		N/A
WASTE DISPOSAL METHOD:
		Waste material must be disposed of in accordance with federal, state and focal environmental control regulations. Empty containers must be handled with care due to product residue and flammable solvent vapor. DO NOT HEAT OR CUT EMPTY CONTAINER WITH ELECTRIC OR GAS TORCH. (See Sections IV. & VIII.)
10. SPECIAL PRECAUTIONS & STORAGE DATA:
STORAGE TEMPERATURE (MIN/MAX):
		Not established
SHELF LIFE:
		Not established
SPECIAL SENSITIVITY:
		Material is hygroscopic.
HANDLING/STORAGE PRECAUTIONS:
		Material is hygroscopic arid containers should tightly sealed to prevent contamination with foreign materials and moisture.

11. SHIPPING INFORMATION:
TECHNICAL SHIPPING NAME:	Polyacrylate/Polyester contains Butyl Acetate Methyl n-Amyl Ketone
FREIGHT CLASS BULK	Synthetic resin
FREIGHT CLASS PACKAGE	Resin, coal tar or petroleum
PRODUCT LABEL	SLB10649
DOT (HM-181) (DOMESTIC SURFACE)
PROPER SHIPPING NAME	Resin Solution
HAZARD CLASS OR DIVISION	3
UN/NA NUMBER	UN1866
PACKAGING GROUP	PG III
DOT PRODUCT RQ lbs (kgs)	46728 lbs (21195.8 kgs)
HAZARD LABEL (s)	Flammable Liquid
HAZARD PLACARD (s)	Flammable
IMO/ IMDG CODE (OCEAN)
PROPER SHIPPING NAME	Resin Solution
HAZARD CLASS DIVISION NUMBER	3.3
UN NUMBER	UN1866
PACKAGING GROUP	III
HAZARD LABEL (s)	Flammable Liquid
HAZARD PLACARD (s)	Flammable Liquid
ICAO / IATA (AIR)
PROPER SHIPPING NAME	Resin Solution
HAZARD CLASS DIVISION NUMBER	3
UN NUMBER	UN1866
SUBSIDIARY RISK	None
PACKING GROUP	III
HAZARD LABEL (s)	Flammable Liquid
RADIOACTIVE?	Non-Radioactive
PASSENGER AIR - MAX. QTY	60L
PASSENGER INSTRUCTION NUMBER	309
CARGO AIR -MAX. QTY	220L
CARGO AIR INSTRUCTION NUMBER	310

12. ANIMAL TOXICITY DATA:
TOXICITY DATA FOR: Crystalline Silica

CARCINOGENICITY:
	In the IARC Monographs, in studies in experimental animals (primarily rats), there were significant increases in the incidences of a denocarcinomas and squamous-cell carcinomas of the lung, and malignant lymphomas of the histiocyte type. In these studies, fibrosis (fibrotic lung damage) was an important part of the biological response to crystalline silica.
TOXICITY DATA FOR: Butyl acetate

ACUTE TOXICITY
ORAL LD50:
	14000 mg/kg (rat)
INHALATION LC50:
	2000 ppm (rat)
EYE EFFECTS:
	Severe irritant, 20 mg (rabbit)
SKIN EFFECTS:
	Moderate irritant, 500 mg/24 H (rabbit)
SUBCHRONIC TOXICITY:
	Rabbits exposed for 1 hour 30 times over 15 weeks to airborne levels of BA between 4600 ppm and 6300 ppm developed degenerative changes in the liver.
TOXICITY DATA FOR: Titanium Dioxide
OTHER TOXICITY DATA:
	Test results indicate that rats developed a statistically significant increase in benign or malignant lung tumors after inhaling extremely high concentrations of titanium dioxide dust (250 mg/m3) for 2 years. At lower concentrations, no significant increase in tumors was found
TOXICITY DATA FOR: MAK
ACUTE TOXICITY
ORAL LD50:
	1670 mg/kg (Rat)
DERMAL LD50:
	12600 mg/kg (Rabbit)
SKIN EFFECTS:
	Mild irritation 10 mg, 24 hours open (Rabbit)
OTHER ACUTE EFFECTS :
	Inhalation LCLo: 4000 ppm, 4 hours (Rat)

13. FEDERAL REGULATORY INFORMATION:
OSHA STATUS :
	This product is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29 CFR 1910.1200.
TSCA STATUS :
	On TSCA Inventory
CERCLA REPORTABLE QUANTITY:
	Butyl Acetate - 5000 lbs.;
SARA TITLE III:
	SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES
		None
	SECTION 311/312 HAZARD CATEGORIES
		Immediate Health Hazard; Delayed Health Hazard
	SECTION 313 TOXIC CHEMICALS
		None
	RCRA STATUS
		When discarded in its purchased form, this product meets the criteria of ignitability, and should be managed as a hazardous waste (EPA Hazardous Waste Number D001).(40 CFR 261.20-24)

14. OTHER REGULATORY INFORMATION:

The following chemicals are specifically listed by individual states; other product specific health and safety data in other sections of the MSDS may also be applicable for state requirements. For details on your regulatory requirements you should contact the appropriate agency in your state.

MATERIAL SAFETY DATA SHEET:

E-700 POLYESTER Part [ A ]

1. CHEMICAL PRODUCT IDENTIFICATION: E-700 POLYESTER

2. COMPOSITION/INFORMATION ON INGREDIENTS:

INGREDIENT NAME /CAS NUMBER

EXPOSURE LIMITS

CONCENTRATION (%)

HAZARDOUS INGREDIENTS

3. PHYSICAL PROPERTIES:

PHYSICAL FORM

COLOR

ODOR

BOILING POINT

MELTING/FREEZING POINT

SOLUBILITY IN WATER

SPECIFIC GRAVITY

BULK DENSITY

% VOLATILE BY WEIGHT

VAPOR PRESSURE

4. FIRE AND EXPLOSION DATA:

FLASH POINT:

FLAMMABLE LIMITS:

EXTINGUISHING MEDIA:

SPECIAL FIRE FIGHTING PROCEDURES:

5. HUMAN HEALTH DATA:

ROUTE (S) OF ENTRY:

HUMAN EFFECTS AND SYMPTOMS OF OVEREXPOSURE:

ACUTE INHALATION

CHRONIC INHALATION

ACUTE SKIN CONTACT

CHRONIC SKIN CONTACT

ACUTE EYE CONTACT

CHRONIC EYE CONTACT

ACUTE INGESTION

CHRONIC INGESTION

CARCINOGENICITY

MEDICAL CONDITIONS

EXPOSURE LIMITS :

6. EMERGENCY AND FIRST AID PROCEDURES:

FIRST AID FOR EYES:

FIRST AID FOR SKIN:

FIRST AID FOR INHALATION:

FIRST AID FOR INGESTION:

NOTE TO PHYSICIAN:

7. EMPLOYEE PROTECTION RECOMMENDATIONS:

EYE PROTECTION REQUIREMENTS:

SKIN PROTECTION REQUIREMENTS:

RESPIRATORY/VENTILATION REQUIREMENT:

MONITORING:

MEDICAL SURVEILLANCE:

ADDITIONAL PROTECTIVE MEASURES:

8. REACTIVITY DATA:

STABILITY:

HAZARDOUS POLYMERIZATION:

INCOMPATIBILITIES:

INSTABILITY CONDITIONS:

DECOMPOSITION PRODUCTS:

9. SPILL AND LEAK PROCEDURES:

SPILL OR LEAK PROCEDURES:

NEUTRALIZATION CHEMICALS

WASTE DISPOSAL METHOD:

10. SPECIAL PRECAUTIONS & STORAGE DATA:

STORAGE TEMPERATURE (MIN/MAX):

SHELF LIFE:

SPECIAL SENSITIVITY:

HANDLING/STORAGE PRECAUTIONS:

11. SHIPPING INFORMATION:

TECHNICAL SHIPPING NAME:

FREIGHT CLASS BULK

FREIGHT CLASS PACKAGE

PRODUCT LABEL

DOT (HM-181) (DOMESTIC SURFACE)

PROPER SHIPPING NAME

HAZARD CLASS OR DIVISION

UN/NA NUMBER

PACKAGING GROUP

DOT PRODUCT RQ lbs (kgs)

HAZARD LABEL (s)

HAZARD PLACARD (s)

IMO/ IMDG CODE (OCEAN)

E-700 POLYESTER
Part [ A ]

INGREDIENT NAME
/CAS NUMBER

INGREDIENT NAME
/CAS NUMBER