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MATERIAL SAFETY DATA SHEET:

E-1000 Polyester 
[ Clear Coat] Part [ A]

 Emergency Number Chem. 
Tel 1-800-255-3924

1. CHEMICAL PRODUCT IDENTIFICATION:  E-1000 Polyester  
Product Name: Formulation 2035 Component I
Product Code: E-10002035
Chemical Family: Polyester Polyol

2. COMPOSITION/INFORMATION ON INGREDIENTS:
INGREDIENT NAME
/CAS NUMBER
EXPOSURE LIMITS
CONCENTRATION (%)
HAZARDOUS INGREDIENTS
Propylene Gycol Monomethyl Ether Acetate
108-65-6  13463-67-7 
OSHA: Not Established
ACGIH: Not Established 		Approx. 20%
*100 ppm TWA (150 pm STEL) recommended based on similarity to Propylene Gycol Monomethyl Ether Acetate
Xylene
1330-20-7
OSHA: 100.00 ppm TWA
150.00 ppm STEl,

ACGIH: 100.00 ppm TWA
150.00 ppm STEL

 Approx. 18%

3. PHYSICAL PROPERTIES:
PHYSICAL FORM
 Liquid
COLOR
 Colorless
ODOR
 Of solvent
BOILING POINT
 Not established 
MELTING/FREEZING POINT
 Not established 
SOLUBILITY IN WATER
 Resin: Insoluble
SPECIFIC GRAVITY 
 1.03
BULK DENSITY
 8.5 lbs/gal
% VOLATILE BY WEIGHT
 Approximately 38%
VAPOR PRESSURE
 Not established
 

4. FIRE AND EXPLOSION DATA:
FLASH POINT:
 Not established {Xylene: 81 F (27.2 C)}
FLAMMABLE LIMITS:
UPPER EXPLOSIVE LIMIT (UEL) (%): 13.1% @ 283 F PMA
LOWER EXPLOSIVE LIMIT (LEL)(%): 1.3% @ 173 F PMA
UPPER EXPLOSIVE LIMIT (UEL)(%): 7.0 Xylene
LOWER EXPLOSIVE LIMIT (LEL)(%): 1.0 Xylene
EXTINGUISHING MEDIA: 
 Dry Chemical; Carbon Dioxide; Foam; Water Spray for large fires.
SPECIAL FIRE FIGHTING PROCEDURES:
Full emergency equipment with self-contained breathing apparatus should be worn. During a fire irritating, toxic gases (see Reactivity Data) and smoke are present from decomposition/combustion. Isolate from heat, electrical equipment, sparks and open flame. Closed container may explode when exposed to extreme heat. Use cold water spray to cool fire-exposed containers to minimize risk of rupture. Solvent vapors may be heavier than air. Under conditions of stagnant air, vapors may build up and travel along the ground to an ignition source which may result in a flash back to the source of the vapors.

5. HUMAN HEALTH DATA:
ROUTE (S) OF ENTRY:
Inhalation; Skin Contact; Skin Absorption; Eye Contact
HUMAN EFFECTS AND SYMPTOMS OF OVEREXPOSURE:
ACUTE INHALATION
Solvent vapors are irritating to the eyes, nose, throat and respiratory tract resulting in red, itchy eyes, dryness the throat and tightness in the chest. Other possible symptoms of overexposure include headache, nausea, narcosis, fatigue and loss of appetite. At 200 ppm of butyl acetate, persons have developed irritation of the eyes, nose and throat. These symptoms were severe at 300 ppm of butyl acetate. Overexposure to crystalline silica and titanium dioxide cause upper respiratory tract irritation. Symptoms may include coughing and shortness of breath.
CHRONIC INHALATION
Chronic exposure to organic solvents has been
associated with various neurotoxic effects including permanent brain and
nervous system damage. Symptoms include loss of memory, loss of
intellectual ability, and loss of coordination. Excessive exposure to
airborne crystalline silica can cause fibrotic lung damage, with scaring
of the lungs and with coughing and shortness of breath. This condition is called "silicosis".
ACUTE SKIN CONTACT
Repeated or prolonged skin contact with solvents can result in dry, defatted and cracked skin causing increased  susceptibility to infection. In addition, irritation (i.e. redness, swelling ) which may develop into dermatitis (inflammation) may occur from skin contact. Solvents can penetrate the skin causing effects similar to those identified under acute inhalation symptoms
CHRONIC SKIN CONTACT
Chronic skin exposure to the solvent may cause effects similar to those identified under chronic inhalation effects.
ACUTE EYE CONTACT
Prolonged contact can cause reddening, swelling, rash, scaling, blistering, and in some cases, skin sensitization: Individuals who have developed a skin sensitization can develop these symptoms as a result of contact with very small amounts of liquid material or as a result of exposure to vapor. See results of intradermal test in Section XII Animal Toxicity Data, SENSITIZATION. Chronic skin exposure to the solvent may cause effects similar to those identified under chronic inhalation effects.
CHRONIC EYE CONTACT
Prolonged vapor contact may cause conjunctivitis.
ACUTE INGESTION 
Can result in irritation in the mouth, stomach tissue and digestive tract. Symptoms can include sore throat, abdominal pain, nausea, vomiting and diarrhea. Vomiting may cause aspiration resulting in chemical pneumonitis.
CHRONIC INGESTION
None known
CARCINOGENICITY
NTP  :  Not listed
IARC  :  Crystalline silica has been classified by IARC as Group 2A - "there is limited evidence of carcinogenicity in humans and
sufficient evidence of carcinogenicity in experimental animals" (IARC Monographs, Vol. 42).
OSHA  :  Not regulated
OTHER : 
MEDICAL CONDITIONS
None determined. 
EXPOSURE LIMITS :
Not established for this product as a whole, refer to Section II for exposure limits of hazardous constituents.

6. EMERGENCY AND FIRST AID PROCEDURES:
FIRST AID FOR EYES:
Flush with clean, lukewarm water (low pressure) for at least 15 minutes while holding eyelids open. Obtain medical attention if irritation persists..
FIRST AID FOR SKIN:
Remove contaminated clothing immediately. Wash affected areas thoroughly with soap and water. Wash contaminated clothing thoroughly before reuse. 
FIRST AID FOR INHALATION:
Move to an area free from risk of further exposure. Administer oxygen or artificial respiration as needed. Obtain medical attention. 
FIRST AID FOR INGESTION:
DO NOT INDUCE VOMITING. Give a glass of milk or water to drink. DO NOT GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. Consult a physician.
NOTE TO PHYSICIAN:
None Mentioned.

7. EMPLOYEE PROTECTION RECOMMENDATIONS:
EYE PROTECTION REQUIREMENTS: 
Liquid chemical goggles or full-face shield. Contact lenses should not be worn.
SKIN PROTECTION REQUIREMENTS: 
Permeation resistant gloves (butyl rubber, nitrile rubber). Cover as much of the exposed skin area as possible with appropriate clothing. If skin creams are used, keep the area protected only by the cream to a minimum.
RESPIRATORY/VENTILATION REQUIREMENT: 
Exhaust ventilation sufficient to keep  airborne concentrations of solvents and other hazardous constituents in t workplace below their respective TLVs or other appropriate exposure limit must be utilized. Exhaust air may need to be cleaned by scrubbers or filters to reduce environmental contamination. Curing ovens must be ventilated to prevent the build up of explosive atmospheres and to prevent off gases from entering the work place. in addition, a respirator that is recommended or approved for use in organic vapor containing environments (air purifying or fresh air ,supplied) may be necessary. In spray applications, an organic vapor/ particulate respirator or air supplied unit is necessary. Consider type of application and environmental concentrations. The use of a positive pressure supplied air respirator is mandatory when: airborne concentrations are not known; when levels are 10 times the appropriate TLV; or if spraying is performed in a confined space or area with limited ventilation. Take into account other materials being used concurrently. Observe OSHA regulations for respirator use (29 CFR 1910.134).
MONITORING:
None Mentioned.
MEDICAL SURVEILLANCE:
None Mentioned.
ADDITIONAL PROTECTIVE MEASURES:
Safety showers and eyewash stations should be available. Educate and train employees in safe use of product. Follow all label instructions.

8. REACTIVITY DATA:
STABILITY:
This is a stable material.
HAZARDOUS POLYMERIZATION: 
Will not occur.
INCOMPATIBILITIES:
Trimethylol propane is used in the manufacture of this resin; therefore, it should not be combined with phosphorus containing materials because highly toxic fumes can be emitted in a fire situation. avoid oxidizers
INSTABILITY CONDITIONS:
None determined
DECOMPOSITION PRODUCTS:
By fire: C0, C02

9. SPILL AND LEAK PROCEDURES:
SPILL OR LEAK PROCEDURES: 
Evacuate non-essential personnel. Remove all sources of ignition and ventilate the area. Equip clean-up crew with appropriate protective equipment (i.e., clothing, respiratory, etc. See Employee Protection Recommendations). Dike or impound spilled material a:: control further spillage if feasible. Notify appropriate authorities if necessary. Cover spill with sawdust, vermiculite, Fuller's earth or other absorbent material; pour liquid decontaminate over spillage and allow to react for at least 10 min. Collect material in open containers and add further amounts of decontamination solution. Remove containers to safe place and cover loosely. Wash down area with liquid decontaminant and flush area with water.
NEUTRALIZATION CHEMICALS 
N/A
WASTE DISPOSAL METHOD:
 Waste material must be disposed of in accordance with federal, state and focal environmental control regulations. Empty containers must be handled with care due to product residue and flammable solvent vapor. DO NOT HEAT OR CUT EMPTY CONTAINER WITH ELECTRIC OR GAS TORCH. (See Sections IV. & VIII.)

10. SPECIAL PRECAUTIONS & STORAGE DATA:
STORAGE TEMPERATURE (MIN/MAX):
32f (0 C ) / 122F (50 C )
SHELF LIFE:
12 months at 77 f (25C) in closed original container.
SPECIAL SENSITIVITY:
Material is hygroscopic.
HANDLING/STORAGE PRECAUTIONS:
Material is hygroscopic containers should tightly sealed to prevent contamination with foreign materials and moisture. Take precations agaist the buildup of electrostatic charges.
Material is flameble--- Keep away from heat, sparks and open flames.

11. SHIPPING INFORMATION:
TECHNICAL SHIPPING NAME:
 Polyester resin contains Propylene Gycol Monomethyl Ether Acetate, Xylene
FREIGHT CLASS BULK
 Synthetic resin
FREIGHT CLASS PACKAGE
 Resin, coal tar or petroleum
PRODUCT LABEL
 Formulation # 20356 Component 1

DOT (HM-181) (DOMESTIC SURFACE)
PROPER SHIPPING NAME
 Paint
HAZARD CLASS OR DIVISION
 3
UN/NA NUMBER
 UN 1263
PACKAGING GROUP
 PG III
DOT PRODUCT RQ lbs (kgs)
 5555 lbs (2519.7 kgs)
HAZARD LABEL (s) 
 Flammable Liquid
HAZARD PLACARD (s) 
 Flammable

IMO/ IMDG CODE (OCEAN)
PROPER SHIPPING NAME
 Paint
HAZARD CLASS DIVISION NUMBER
 3.3
UN NUMBER
 UN 1263
PACKAGING GROUP
 III
HAZARD LABEL (s)
 Flammable Liquid
HAZARD PLACARD (s)
 Flammable Liquid

ICAO / IATA (AIR)
PROPER SHIPPING NAME
 Paint
HAZARD CLASS DIVISION NUMBER
 3
UN NUMBER
 UN 1263
SUBSIDIARY RISK
 None
PACKING GROUP
 III
HAZARD LABEL (s)
 Flammable Liquid
RADIOACTIVE? 
 Non-Radioactive
PASSENGER AIR - MAX. QTY
 60L 
PASSENGER INSTRUCTION NUMBER
 309 
CARGO AIR -MAX. QTY
 220L 
CARGO AIR INSTRUCTION NUMBER
 310

12. ANIMAL TOXICITY DATA:
TOXICITY DATA FOR: PMA
ACUTE TOXICITY
ORAL LD50: 
Greater Than 8500 mg/kg (rat)
Dermal LD50
5000 mg/kg (rabbit)
INHALATION LC50:
4300 ppm (rat)
EYE EFFECTS:
Slight transient injury and irritation (rabbit)
SKIN EFFECTS:
Slight iritation and scaling (rabbit)
Sensitization
Negative ( Guinea Pig )
OTHER ACUTE EFFECTS :
Chronic inhalation of PMA at very high exposures ( 300 ppm ) caused a slight increase in liver weight in female rats and mice, a slight effect on kidney fucntioon and slight to moderate injury to the linning of the nose in rats and mice. The latter effect was more sever in mice.
TOXICITY DATA FOR: XYLENE
ACUTE TOXICITY
ORAL LD50:
4300 mg/kg (Rat)
DERMAL LD50:
Greater Than 1700 mg/kg (Rabbit)
INHILATION:
Mild  to Severe irritation  (Rabbit)
SKIN EFFECTS :
Modderate Iritation ( Rabbit )

13. FEDERAL REGULATORY INFORMATION:
OSHA STATUS :
This product is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29 CFR 1910.1200.
TSCA STATUS : 
On TSCA Inventory
CERCLA REPORTABLE QUANTITY:
XYLENE - 1000 lbs.;
SARA TITLE III:
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES
None
SECTION 311/312 HAZARD CATEGORIES
Immediate Health Hazard; Delayed Health Hazard; Fire Hazard
SECTION 313 TOXIC CHEMICALS
XYLENE  (CAS# 1330-20-7 ) Approx. 18%
RCRA STATUS
When discarded in its purchased form, this product meets the criteria of ignitability, and should be managed as a hazardous waste (EPA Hazardous Waste Number D001).(40 CFR 261.20-24)

14. OTHER REGULATORY INFORMATION:
The following chemicals are specifically listed by individual states; other product specific health and safety data in other sections of the MSDS may also be applicable for state requirements. For details on your regulatory requirements you should contact the appropriate agency in your state.

INGREDIENT NAME
/CAS NUMBER
CONCENTRATION
STATE CODE
Propolene Glycol Monomethyl Ether Acetate
108-65-6  
Approx. 20% PA3,  NJ4
       
Polyester Polyol
NJTSRN (31765300002)-5992P
Approx. 46% PA3 , NJ4
CA =
  California Proposition 65
MA = 
 Massachusetts Hazardous Substance List
NJ1 = 
 New Jersey Hazardous Substance List
NJ2 =
 New Jersey Environmental Hazardous Substance List
NJ4 =
 New Jersey Other - included in 5 predominant ingredients > 1% 
NJTSRN =
 New Jersey Trade Secret Registry Number
PA1= 
 Pennsylvania Hazardous Substance List 
PA3 =
 Pennsylvania Non-
hazardous present at 3% or greater.

 

15. APPROVALS:
REASON FOR ISSUE Domestic Sample
PREPARED BY B. J. Gambino H.
APPROVED BY H. E. Myer
APPROVAL DATE 01/03/96
SUPERSEDES DATE none
MSDS NUMBER 25228

This information is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Environmental Protective Coatings, Inc. . The data on  this sheet relates only to the specific material designated herein. Environmental Protective Coatings, Inc. assumes no legal responsibility for use or reliance upon these data.
 
 

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